Everything You Need To Know To Find The Best stainless steel heat exchanger tube

Material pricing and availability can fluctuate based on market supply and demand, the quantity required for your exchanger, and the components needed. Copper was a low-cost option a few years ago, but now due to supply, it is more expensive than stainless steel. Conversely, Titanium used to be one of the most expensive alloys but is now more reasonably priced. Typically, the more nickel content in a metal, the higher the price.

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Here is the relative ranking for some of the common metal material options by price from highest to lowest:

1. MOST EXPENSIVE: Nickel 200, also known as UNS N, is a commercially pure nickel alloy. It is one of the most widely used nickel alloys due to its excellent mechanical properties and high corrosion resistance. Nickel 200 consists of 99.6% pure nickel, with small amounts of impurities such as iron, copper, and manganese.

2. Alloy 625, also known as Inconel 625, is a nickel-based superalloy known for its excellent strength, corrosion resistance, and high temperature performance. It is composed mainly of nickel, with significant amounts of chromium and molybdenum, along with smaller additions of niobium, iron, and other elements. Alloy 625 is widely used in various industries, including aerospace, chemical processing, oil and gas, and marine applications.

3. Monel 400 is a nickel-copper alloy known for its excellent corrosion resistance in various environments. It is composed of approximately 67% nickel and 30% copper, with small amounts of iron, manganese, carbon, and silicon. Monel 400 is highly resistant to corrosive substances such as acids, alkaline solutions, and saltwater. It is often used in applications where resistance to corrosion, erosion, and high temperatures are essential.

4. Hastelloy C22 is a nickel-chromium-molybdenum alloy known for its exceptional corrosion resistance in a wide range of aggressive environments. Hastelloy C22 is particularly resistant to pitting, crevice corrosion, and stress corrosion cracking. Hastelloy C22 is often chosen for chemical processing and waste treatment.

5. Hastelloy C-276 is a nickel-molybdenum-chromium alloy that is renowned for its corrosion resistance and high-performance properties. While similar to Hastelloy C22, Hastelloy C-276 has lower chromium content, easier weldability, and slightly higher upper temperature limits. Hastelloy C-276 is used in various industries, including chemical processing, pollution control, pulp and paper production, and petrochemical applications.

6. Duplex  is a super duplex stainless steel alloy that offers excellent strength, corrosion resistance, and durability. It is part of the duplex stainless steel family, which combines the desirable properties of both austenitic and ferritic stainless steels. Duplex is characterized by its high levels of chromium, molybdenum, and nitrogen, providing superior resistance to corrosion and high mechanical strength.

7. AL6XN is a high-performance austenitic stainless steel alloy that offers exceptional corrosion resistance and mechanical properties. It is specifically designed to withstand highly corrosive environments, including chloride-rich environments, acids, and seawater. AL6XN is known for its versatility, making it suitable for various applications in industries such as chemical processing, pulp and paper, oil and gas, and desalination.

8. Titanium is a lightweight metal known for its high strength, low density, and excellent corrosion resistance. Titanium is widely used in various industries due to its unique combination of properties.

9. Duplex is a stainless steel alloy with a combination of austenitic and ferritic microstructures, known as a duplex structure. It offers excellent strength, corrosion resistance, and durability, making it suitable for a wide range of applications. Duplex is highly popular in industries such as oil and gas, chemical processing, marine, and pulp and paper.

10. 316L stainless steel is a commonly used grade of stainless steel known for its corrosion resistance, high strength, and versatility. It is an austenitic stainless steel alloy with low carbon content, making it suitable for various applications where resistance to corrosive environments is essential. It is widely used in marine applications, chemical processing, dairy, and pharmaceuticals.

10. 304L stainless steel is a commonly used grade of stainless steel known for its corrosion resistance, versatility, and ease of fabrication. It is an austenitic stainless steel alloy with low carbon content, which enhances its weldability and reduces the risk of sensitization to intergranular corrosion. In comparison to 316L SS, 304L SS has no molybdenum content and it&#;s less resistant to chloride-induce corrosion. It is suitable for general-purpose uses that don&#;t require the enhanced corrosion resistance of 316L SS.

12. LEAST EXPENSIVE: Carbon steel is a type of steel that primarily consists of iron and carbon, with other elements present in smaller amounts. It is one of the most commonly used materials in the manufacturing and construction industries due to its affordability, strength, and versatility.

Typically, the higher priced alloys are also in shorter supply, due to lower demand and the higher cost of carrying inventory. This directly affects the lead-time of these materials, often by 2-4 times that of more common alloys like carbon steel and stainless steel. Quantity of these higher alloys can also greatly affect price. Steel mills typically don&#;t run small batches of tubes or plate or they will charge for the entire mill run if they do.

Time to read: 6 min

One of my favorite jobs as a mechanical engineer was as a heat exchanger designer for commercial aerospace. While it may appear straightforward, there are a lot of  considerations in good heat exchanger design, including: 

• Mechanical strength to resist bursting due to high pressure
• Geometry constraints (fitting effective heat exchangers into small footprints) 
• Fluid flow optimization and calculations 
• Pressure drop optimization
• Mechanical power needed to overcome fluid friction
• Heat transfer rate between fluids
• Fluid flow channel sizing and geometry (surface area density)
• Material selection for the coefficient of friction, coefficient of thermal expansion, heat transfer characteristics, and material compatibility

Now, I could rant for days about optimal fin design, methods for joining plates and fins, and even flow-stream mechanical energy losses, but this article is focused on material selection for heat exchanger design. Choosing the right material is critical to the success of your heat exchanger design because making a good choice enhances your design, while the wrong choice can cause it to fail. 

What Impact Does Material Selection Have on Heat Exchanger Performance?

Heat exchanger material should be chosen based on its physical material properties like thermal conductivity, temperature resistance, corrosion resistance, and strength &#; plus non-stable supply chain considerations such as cost and availability. The wrong material can lead to higher cost and longer production times if it&#;s more difficult to machine and weld. 

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Material selection has a direct impact on the ability of the heat exchanger to exchange heat from one fluid to another. If you select a poor material, you&#;ll suffer negative impacts on the rate of heat transfer, drops in pressure, and you may even require excess mechanical power. On the other hand, correct material selection for heat exchanger design allows you to optimize performance, efficiency, cost, and potentially find savings in weight or achieve a smaller footprint.

What Material Properties Should You Look for In Heat Exchanger Design?

As mentioned above, these are the properties you should look to optimize when designing a heat exchanger: 

• Thermal Conductivity: Thermal conductivity is the measure of a material&#;s ability to transfer heat. Higher thermal conductivity materials allow more efficient heat transfer, which improves the performance of your design. 
• Temperature Resistance: Temperature resistance is the measure of a material&#;s ability to withstand high temperatures without deformation or compromising strength. 
• Density//Weight: Often, heat exchangers are designed for applications that require lightweight parts or where increases in weight decrease fuel efficiency &#; as with aerospace applications. 
• Corrosion Resistance: Corrosion resistance is the measure of a material&#;s ability to resist corrosion from chemical and environmental conditions and is especially critical if a heat exchanger will be subjected to harsh conditions. 
• Strength: Strength is the measure of a material&#;s ability to resist mechanical forces. Increased mechanical strength is required for applications that contain fluids at high pressure or will be subjected to heavier loads. 
• Cost and Availability: Cost and availability are self explanatory &#; you always want the best functional materials at the lowest cost.

Now, of course, not all materials provide an optimized combination of mechanical properties, cost, and availability &#; you&#;ll have to sacrifice one factor over the others to complete your design. 

Pro-tip: To see how material properties impact CNC machining and how to design for manufacturability, check out our on-demand webinar, DFM for CNC Machining: Minimize the Challenges with Design for CNC Machining. 

The Best Materials for Heat Exchanger Design

The best materials for heat exchanger design are materials with a combination of high thermal conductivity, high temperature resistance, excellent corrosion resistance, good mechanical strength, low cost, and wide availability. 

Copper is the most well-known metal with high electrical conductivity. Copper also has a high thermal conductivity due to its lattice-like atomic structure, which allows efficient energy conduction throughout the material. The number of free electrons in each atom of copper also allows for fast and efficient movement of energy via thermal or electrical conduction. This high thermal conductivity means that heat transfer from the hot to cold fluid will occur as efficiently as possible and with as much speed as possible. 

Copper also provides excellent corrosion resistance, fluid compatibility, and good mechanical strength. Copper comes in many alloys that are generally readily available and relatively inexpensive. In addition, it&#;s relatively easy to machine and weld, making it suitable for multiple manufacturing methods. Copper is especially suitable for tube and shell heat exchangers thanks to its high ductility &#; which allows it to be drawn into thin-walled tubes or extruded into small wires without fracturing.

Stainless steel is known for its high mechanical strength and excellent corrosion resistance, which comes from its naturally occurring, protective oxide layer. Stainless steel also has good thermal conductivity, which is why the material is an optimal choice for heat exchangers that must withstand ultra-high temperatures, high burst pressure, and extremely harsh environments. 

Stainless steel is stronger than aluminum, carbon steel, and copper, and its mechanical strength is preserved at higher temperatures than other common heat exchanger metals. This reduces the potential for distortion or warping over extended exposure to extreme temperatures. Stainless steel is also simple to machine and weld, which makes it easier to fabricate and assemble heat exchangers. 

For most commercial aircraft, various grades of aluminum are the predominant choice for heat exchanger material because it&#;s strong, yet lightweight. It&#;s the most common metal on earth, so it&#;s readily available and cost-effective. Aluminum also has a naturally occurring, protective oxide layer that can be modified to be stronger. Aluminum is ductile enough to be drawn into thin tubes or rolled into thin sheets and formed into fins with complex geometries. Aluminum also has excellent thermal conductivity, though it isn&#;t able to withstand temperatures above a few hundred degrees Fahrenheit. 

Aluminum can be readily brazed with methods like aluminum fluxless vacuum brazing, which creates a strong joint that can withstand the pressure of a heat exchanger. During brazing, the aluminum oxide layer cracks because it&#;s more brittle than the underlying metal. This cracking occurs at high temperatures right before the braze metal melts and fills the gaps between the oxide layer, and a gettering agent is used to prevent the oxides from reforming. While aluminum isn&#;t suitable for all heat exchanger applications, it&#;s generally the first material I would recommend. 

Titanium has only been prominently utilized in manufacturing since the early s. (Though it was discovered in by an English pastor!) Titanium has many excellent material properties that make it suitable for heat exchanger construction &#; it&#;s lightweight, corrosion-resistant, and has good heat transfer properties. I think of titanium as a supercharged cousin of aluminum that provides many of the same valuable material properties, but on a higher scale &#; except for its thermal conductivity, which is lower than aluminum. Still, titanium boasts the highest operating temperature on this list, and that tradeoff may be necessary in some applications. 

Titanium is about 1.5x more dense than aluminum, but its strength is 4-5x higher than aluminum, so using titanium can result in significant weight savings. However, a common misconception is that titanium is lighter weight than aluminum &#; the truth is that you get the same load capacity from less titanium than you get with the same amount of aluminum. This is why many aerospace companies, car manufacturers, and even medical device companies are utilizing titanium more in order to meet requirements to minimize weight and increase strength. 

Comparison of the Best Materials for Heat Exchanger Design

Now that you know the pros and cons of the materials, you can utilize the tables below &#; which have the key data points for each &#; to simplify material selection for your next heat exchanger design: 

Thermal Conductivity (BTU/hr*ft*F)Copper6.95Stainless Steel0.285Aluminum4.14Titanium0.15 Highest Operating Temperature (F)CopperStainless SteelAluminum300Titanium Density (lb/in^3) @ Room Temp (68F)Copper0.323Stainless Steel0.285Aluminum0.098Titanium0.163 Corrosion ResistanceCopperHighStainless SteelHighAluminumModerateTitaniumHigh Tensile Strength (lb/in^2)CopperStainless SteelAluminumTitanium

Key Takeaways: Heat Exchanger Material Selection

1. How do you select a material for a heat exchanger?
   
   Heat exchanger selection should involve a tradeoff between material properties like thermal conductivity, tensile strength, maximum operating temperature, density, and corrosion resistance versus availability and cost. 

2. What is the best material to use for a heat exchanger?
   
   Our recommendations for heat exchanger material are copper, stainless steel, aluminum or titanium.

3. What are the factors for selecting reliable heat exchanger tube materials?
   
   Fluid compatibility, tensile strength, and ductility are all important factors to consider when selecting a material for heat exchanger tubing. 

4. What is the best material for condensing heat exchanger for steam?

Stainless steel is a good choice for handling condensing steam heat exchanger applications because it&#;s corrosion-resistant, resistant to high temperatures, and thermally conductive. 

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